Water is one of the few substances that exhibits about 70 documented anomalies. These anomalies concern its thermodynamic, mechanical, structural, and even acoustic properties. They arise from the cooperative nature of hydrogen bonds and explain why water is the basis of life as we know it.
N.B.: Hydrogen bonds are directional dipole-dipole interactions between a hydrogen atom bonded to a highly electronegative atom (such as oxygen) and another electronegative atom. In water, each molecule can form up to four hydrogen bonds, creating a dynamic network. This network is the primary cause of most of water's anomalies, including its maximum density, high specific heat, and non-monotonic viscosity.
The viscosity of water is one of its most intriguing anomalies. Unlike most liquids, its viscosity does not decrease linearly with temperature. It exhibits a minimum around 30 °C, then slightly increases as the temperature approaches 0 °C. This behavior, called non-monotonic viscosity, is due to the dynamic reorganization of the hydrogen bond network, which strengthens at low temperatures, slowing molecular movement.
Under extreme conditions, such as in cold and low-density regions of interstellar space, water molecules can form highly ordered structures even at very low density and temperature. Theoretical studies and simulations suggest that this interstellar water could exhibit extremely high viscosity, comparable to or even greater than that of honey on Earth. This phenomenon is explained by the quasi-permanent presence of strongly correlated hydrogen bonds and the absence of thermal disturbances.
Under conditions of extremely high viscosity, such as those observed in certain space environments or at low temperatures, water can act as a true structuring solvent.
The network of strongly correlated hydrogen bonds gives water the ability to stick to neighboring molecules, stabilizing their relative position and limiting their diffusion.
This phenomenon allows water to trap and encapsulate molecules, forming protective micro-environments that can:
N.B.: Molecular encapsulation by water is a direct consequence of extreme viscosity and the structured hydrogen network. This property could play a fundamental role in prebiotic chemistry and the formation of the first molecular building blocks in the universe.
Anomaly | Family | Observation | Consequences | Comment |
---|---|---|---|---|
Maximum density (densest liquid at 4 °C) | Thermodynamic | Reaches 1.000 g/cm³ at 4 °C, then decreases at lower temperatures | Stratification of lakes and oceans, protection of aquatic organisms during winter, local climate regulation | Tetrahedral structure of the hydrogen bond network |
Non-monotonic viscosity (minimum around 30 °C) | Dynamic | Approximately 0.797 mPa·s at 25 °C, non-linear variation with temperature | Optimization of cellular transport, influence on ocean dynamics and nutrient circulation, impact on molecular diffusion of substances | Dynamic reorganization of hydrogen bonds |
High specific heat (very large heat capacity) | Thermodynamic | ≈ 4.18 J·g⁻¹·K⁻¹ at 25 °C, significantly higher than similar liquids | Thermal stabilization of aquatic and terrestrial ecosystems, global climate regulation, protection against sudden temperature changes | Energy required to break the H-bond network |
High dielectric constant (strong polarity) | Optical/Dielectric | ≈ 78.5 at 25 °C, decreases with increasing temperature | Allows efficient dissolution of salts and polar molecules, influences chemical and biochemical reactions, impacts electrical properties of solutions | High polarity due to hydrogen bonds |
Abnormal molecular diffusion (increases in supercooling) | Dynamic | Diffusion of ≈ 2.3×10⁻⁵ cm²/s at 25 °C, increases at temperatures below 0 °C | Importance in cryobiology, influence on amorphous ice formation, role in intracellular transport at low temperature | Rapid rearrangements of the hydrogen bond network |
Minimum speed of sound (≈74 °C) | Thermodynamic | ≈ 1402 m/s at 74 °C, varies non-linearly with temperature | Impact on acoustic propagation in oceans and ice, useful in geophysics and underwater sonar | Abnormal local density and compressibility |
Very high surface tension (enhanced capillarity) | Structural | ≈ 72.8 mN/m at 20 °C, higher than most simple liquids | Facilitates capillarity in plants and soils, enables certain animal locomotion on water, influences liquid-gas interfaces | Strengthening of the hydrogen bond network at the surface |
Minimum compressibility (46 °C) | Thermodynamic | ≈ 4.6×10⁻¹⁰ Pa⁻¹, decreases with increasing temperature then increases again | Attenuation of pressure waves in oceans and organisms, role in mechanical protection of cells and biological tissues | H-bond network structure resistant to compression |
Anomaly | Family | Observation | Consequences | Comment |
Ice polymorphs (≥17 forms) | Structural | Ice I to VII, different densities and crystalline structures depending on pressure/temperature | Influence on the formation and stability of planetary ices, role in extraterrestrial geology and climatology | Different H-bond arrangements depending on pressure/temperature |
Freezing point under pressure (decrease under pressure) | Thermodynamic | Decreases from 0 °C to -22 °C at 2000 atm | Melting ice in glaciers and underwater, impact on the dynamics of ice caps and cryogenics | Hydrogen bond network destabilized by pressure |
Expansion during solidification (ice less dense) | Structural | Volume increases by ≈ 9% during freezing | Buoyancy of ice protecting aquatic life, impact on erosion and natural habitats | Fixed and open H-bond network in ice |
High heat of vaporization (very large latent heat) | Thermodynamic | ≈ 40.7 kJ/mol at 100 °C | Earth's thermal regulation, slow evaporation, temperature stabilization in ecosystems | Massive breaking of hydrogen bonds to transition to vapor |
High boiling point (100 °C at 1 atm) | Thermodynamic | 100 °C at 1 atm, significantly higher than comparable liquids | Maintenance of liquid water under various conditions, essential for life and industry | Cohesive H-bond network preventing rapid evaporation |
High solvation capacity (universal solvent) | Optical/Dielectric | Significant solubility for most salts and polar molecules | Basis of aqueous chemistry and biology, allows dissolution and transport of nutrients and ions | Polarity and hydrogen bonds favor hydration |
Supercooling | Dynamic | Water can remain liquid down to -40 °C under controlled conditions | Allows survival of certain cells and organisms, influences crystal formation in nature and industry | Flexible H-bond network delaying crystallization |
Mpemba effect (hot water freezes faster than cold water) | Thermodynamic | Occasional, depends on initial temperature, convection, and supercooling | Influences freezing in nature and laboratory experiments, shows the complexity of the H-bond network | Effect still partially misunderstood, linked to hydrogen bonds and evaporation |
Anomaly | Family | Observation | Consequences | Comment |
Extreme capillarity and adhesion | Structural | Rise of water in very fine tubes or plant xylems | Transport of water and nutrients in plants, enables certain animal locomotion on water | Strong surface tension effect and solid H-bond network |
Exceptional ionic conductivity (Grotthuss mechanism) | Dynamic | Protons and hydroxide ions move at high speed, much faster than classical molecular diffusion | Acceleration of acid-base reactions, rapid transport of electrical charges in solutions | H-bonds facilitate the "jump" of protons between molecules |
Transparency over a wide spectrum | Optical | Low absorption in the visible, increases in the IR | Allows underwater photosynthesis, light penetration in the ocean | Molecular structure and polarity result in low energy losses |
Supercooling | Dynamic | Remains liquid down to -40 °C under controlled conditions | Allows survival of cells and organisms, influences natural and industrial crystallization | Flexible H-bond network delaying ice formation |
Thermal anomalies in deep oceans | Thermodynamic | Liquid water at T<0 °C under high pressure (≈1000–4000 atm) | Maintenance of liquid water in the abyss, impact on ocean circulation and deep ecosystems | H-bond network stabilized by pressure |
Fluctuating local structure (dense and open micro-domains) | Structural | Coexistence of areas with slightly different densities at the nanometric scale | Influences solubility, diffusion, and chemical reactions in solution | Rapid rearrangements of H-bonds at the molecular scale |
Theoretical molecular superfluidity | Dynamic | Simulation: quasi-frictionless movement of confined molecules | Facilitates encapsulation and selective mobility of certain molecules, possible role in prebiotic chemistry | Theoretical phenomenon linked to the H-bond network and extreme confinement |
Mpemba effect (hot water freezes faster than cold water) | Thermodynamic | Occasional, depends on initial temperature, convection, and supercooling | Influences freezing in nature and laboratory experiments, shows the complexity of the H-bond network | Effect still partially misunderstood, linked to hydrogen bonds and evaporation |
Anomaly | Family | Observation | Consequences | Comment |
Extreme capillarity and adhesion | Structural | Rise of water in very fine tubes or plant xylems | Transport of water and nutrients in plants, enables certain animal locomotion on water | Strong surface tension effect and solid H-bond network |
Exceptional ionic conductivity (Grotthuss mechanism) | Dynamic | Protons and hydroxide ions move at high speed, much faster than classical molecular diffusion | Acceleration of acid-base reactions, rapid transport of electrical charges in solutions | H-bonds facilitate the "jump" of protons between molecules |
Transparency over a wide spectrum | Optical | Low absorption in the visible, increases in the IR | Allows underwater photosynthesis, light penetration in the ocean | Molecular structure and polarity result in low energy losses |
Supercooling | Dynamic | Remains liquid down to -40 °C under controlled conditions | Allows survival of cells and organisms, influences natural and industrial crystallization | Flexible H-bond network delaying ice formation |
Thermal anomalies in deep oceans | Thermodynamic | Liquid water at T<0 °C under high pressure (≈1000–4000 atm) | Maintenance of liquid water in the abyss, impact on ocean circulation and deep ecosystems | H-bond network stabilized by pressure |
Fluctuating local structure (dense and open micro-domains) | Structural | Coexistence of areas with slightly different densities at the nanometric scale | Influences solubility, diffusion, and chemical reactions in solution | Rapid rearrangements of H-bonds at the molecular scale |
Theoretical molecular superfluidity | Dynamic | Simulation: quasi-frictionless movement of confined molecules | Facilitates encapsulation and selective mobility of certain molecules, possible role in prebiotic chemistry | Theoretical phenomenon linked to the H-bond network and extreme confinement |
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