The Toxic Legacy of Acid Rain

Acid Rain: A Silent Threat

Acid rain is one of the most persistent environmental legacies of the industrial era. This phenomenon, first identified in the 19th century by Scottish chemist Robert Angus Smith (1817-1884), reached dramatic proportions in the 20th century, becoming a major global environmental issue.

The 19th-century Industrial Revolution marked the beginning of a significant increase in acidifying pollutant emissions. The work of Swedish scientist Svante Odén (1924-1986) in the 1960s established the link between industrial emissions and the acidification of Scandinavian lakes, alerting the international scientific community.

Acidity peaked in the 1970s and 1980s in Europe and North America, with pH values dropping as low as 4.0, or even 3.0 in heavily industrialized regions.

The Mechanism of Acid Rain: pH and Precipitation

Acid rain refers to any form of precipitation with a pH below 5.6, the natural acidity level of rainwater in equilibrium with atmospheric carbon dioxide.

Its formation is primarily due to atmospheric pollutants such as sulfur dioxide (SO₂) and nitrogen oxides (NO_x), mainly from the combustion of fossil fuels.

These compounds undergo oxidation reactions in the atmosphere, transforming into strong acids: pH < 1, as strong acids like sulfuric acid (H₂SO₄) and nitric acid (HNO₃) typically have very low pH levels, often below 1 when concentrated.

\( \text{SO}_3 + \text{H}_2\text{O} \rightarrow \text{H}_2\text{SO}_4 \) (sulfuric acid)
Sulfur trioxide molecules attach to water droplets in the atmosphere. This reaction represents the hydration of SO₃ to form sulfuric acid. SO₃ is an acidic oxide that reacts violently with water. This is the primary source of acidity in acid rain.

\( 2\text{NO}_2 + \text{H}_2\text{O} \rightarrow \text{HNO}_3 + \text{HNO}_2 \) (nitric and nitrous acids)
Nitrogen dioxide gas dissolves in water. This reaction is a dismutation where nitrogen dioxide (NO₂) acts as both an oxidant and a reductant. Nitric acid (HNO₃) is stable and contributes durably to acidity. Nitrous acid (HNO₂) decomposes in sunlight and can recreate highly reactive particles that clean pollutants from the atmosphere.

Source: U.S. Environmental Protection Agency and European Environment Agency.

Ecological Impacts of Acid Rain

Impacts on Aquatic Ecosystems

The acidification of lakes and rivers causes the release of toxic aluminum (Al³⁺) from soils, leading to the gradual disappearance of many fish and aquatic invertebrate species.

Impacts on Forests and Soils

Acid rain leaches essential nutrients such as calcium (Ca) and magnesium (Mg2+) from soils while mobilizing toxic heavy metals like aluminum. This phenomenon caused forest decline (Waldsterben) in Central European forests during the 1980s.

Impacts on Monuments and Buildings

Sulfuric acid (H₂SO₄) reacts with limestone (CaCO₃) in monuments: \( \text{CaCO}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{CaSO}_4 + \text{CO}_2 + \text{H}_2\text{O} \)
This reaction accelerates the erosion of historical architectural heritage.

SO₂ Emissions Status in 2025

Faced with the scale of the problem, several international agreements were concluded, including the Convention on Long-Range Transboundary Air Pollution (1979) and its Gothenburg Protocol (1999), which imposed drastic reductions in SO₂ and NO_x emissions.

Flue gas desulfurization and selective catalytic reduction techniques have led to a significant decrease in emissions in industrialized countries, with a reduction of over 70% in SO₂ emissions in Europe since 1990.

Source: European Environment Agency and United Nations Economic Commission for Europe.

Current Perspectives and Future Challenges

A Contrasting Global Situation

While developed countries have largely controlled acid rain, the situation remains concerning in rapidly industrializing regions, particularly in Asia. China, for example, experienced an acidification peak comparable to Europe's in the 1980s before implementing drastic reduction policies starting in the 2010s.

The Persistence of Long-Term Effects

The current challenge lies in the persistence of long-term effects, with slow recovery of aquatic and forest ecosystems, sometimes requiring active neutralization operations.

Liming: An Essential Corrective Solution

Liming soils and lakes is an essential corrective solution to mitigate the effects of acid rain. This technique, widely used in Scandinavia and Central Europe, involves spreading limestone to neutralize persistent acidity. Although liming is only a palliative response to pollutant emissions, it has saved countless aquatic and forest ecosystems while waiting for source reductions in acidifying emissions.

Current Global SO₂ Emissions

Conclusion

Acid rain represents a textbook case of the environmental impacts of industrialization, but also demonstrates humanity's ability to address major ecological challenges through international cooperation, technological innovation, and regulation. This poisoned legacy reminds us of the importance of a preventive approach to new environmental challenges, particularly climate change.