我们所看到的一切都由原子构成,许多原子源于希腊语"atomos"(不可分割)。早在公元前4世纪,希腊哲学家留基伯和德谟克利特就提出假说:所有物质都由永恒运动、极其坚固且不灭的微小粒子组成。如今我们对原子有了更精确的认识——它并非不可分割。
自1811年起,我们便已知晓其大致尺寸——阿梅代奥·阿伏伽德罗估算原子大小约为10^-10米。1911年,欧内斯特·卢瑟福明确了原子结构,并给出原子核的尺寸量级为10^-14米。
关于原子的大小,我们常提及原子轨道,即环绕原子核的电子云。这种电子云的理论直径范围从氦原子的62皮米(pm)到铯原子的596皮米不等。物质的本性并不简单,这一微小距离会因周围原子的化学性质而变化。
尽管原子核集中了原子的大部分质量(99.99%),但我们也能知道其质量:对于稳定原子,其质量范围从氢的1.674×10^-24克到铀的3.953×10^-22克。
我们也知道它的组成,内部有一个原子核和一个占据整个原子空间范围的电子云,因为电子云的尺寸比原子核大一万倍以上。更令人惊叹的是,我们甚至知道宇宙中的原子数量,这个数字极其庞大,如果要写出来,需要写一个1后面跟着72个零。
经典物理学无法解释原子的稳定性,因为在经典物理学中,带负电的微粒电子与带正电的质子构成了一对矛盾。
在经典物理学中,物质应当消失、湮灭,因为电子绕原子核辐射时会损失能量(根据麦克斯韦理论),因此应当坠入原子核。这意味着在经典理论的框架内,原子的稳定性是无法理解的。
20世纪的科学天才们在1924年解决了这一悖论,这得益于路易·德布罗意(1892-1987)的波动力学,该理论于1926年由埃尔温·薛定谔(1887-1961)推广,薛定谔与保罗·狄拉克(1902-1984)因被称为薛定谔方程的波动方程共同获得1933年诺贝尔物理学奖。
在量子力学中,不进行测量就无法确切知道某个参数的值。数学理论描述状态时,并非通过精确的速度和位置组合,而是通过波函数(状态向量),它可以计算粒子出现在某一点的概率。由此产生了量子力学的概率性质,该理论预言粒子同时也是波,而不再仅仅是物质点。
电子通过电磁力与原子核相互作用,占据原子轨道;而核子则通过核力被束缚在原子核内部。
电子云在原子核周围分层排列成量子化的能级,定义了电子层和亚层。核子也分布在核壳层中,不过一种相当便捷的模型——液滴模型——使核结构的描述更为普及。
多个原子可以通过其电子彼此建立化学键,通常原子的化学性质由其电子排布决定,而电子排布又取决于原子核中的质子数量。这个数量被称为原子序数,它定义了一种化学元素。
最接近物质层面,一张纯金(Au 100)薄片的表面在此通过扫描隧道显微镜详细呈现。图像中可见的金原子在金晶体结构上规则排列。这张原子图像由埃因霍温理工大学的Erwin Rossen于2006年使用低温Omicron STM拍摄。
某些原子的理论原子半径(计算值),单位为皮米(10⁻¹²米)。原子半径是指相邻两个原子核之间距离的一半。本表所列数值仅供参考。
| Size of atoms in picometers (pm) | |||||||
| (1 pm = 10-12 meter) | |||||||
| size | size | size | size | ||||
| H Hydrogen
: number of electron by energy levels 1 |
53 | Ca Calcium
: number of electron by energy levels 2, 8, 8, 2 |
194 | Y Yttrium
: number of electron by energy levels 2, 8, 18, 9, 2 |
212 | Hf Hafnium
: number of electron by energy levels 2, 8, 18, 32, 10, 2 |
208 |
| He Helium
: number of electron by energy levels 2 |
31 | Sc Scandium
: number of electron by energy levels 2, 8, 9, 2 |
184 | Zr Zirconium
: number of electron by energy levels 2, 8, 18, 10, 2 |
206 | Ta Tantalum
: number of electron by energy levels 2, 8, 18, 32, 11, 2 |
200 |
| Li Lithium
: number of electron by energy levels 2, 1 |
167 | Ti Titanium
: number of electron by energy levels 2, 8, 10, 2 |
176 | Nb Niobium
: number of electron by energy levels 2, 8, 18, 12, 1 |
198 | W Tungsten
: number of electron by energy levels 2, 8, 18, 32, 12, 2 |
193 |
| Be Beryllium
: number of electron by energy levels 2, 2 |
112 | V Vanadium
: number of electron by energy levels 2, 8, 11, 2 |
171 | Mo Molybdenum
: number of electron by energy levels 2, 8, 18, 13, 1 |
190 | Re Rhenium
: number of electron by energy levels 2, 8, 18, 32, 13, 2 |
188 |
| B Boron
: number of electron by energy levels 2, 2 |
87 | Cr Chromium
: number of electron by energy levels 2, 8, 13, 1 |
166 | Tc Technetium
: number of electron by energy levels 2, 8, 18, 13, 2 |
183 | Os Osmium
: number of electron by energy levels 2, 8, 18, 32, 14, 2 |
185 |
| C Carbon
: number of electron by energy levels 2 ,4 |
67 | Mn Manganese
: number of electron by energy levels 2, 8, 13, 2 |
161 | Ru Ruthenium
: number of electron by energy levels 2, 8, 18, 15, 1 |
178 | Ir Iridium
: number of electron by energy levels 2, 8, 18, 32, 15, 2 |
180 |
| N Nitrogen
: number of electron by energy levels 2, 5 |
56 | Fe Iron
: number of electron by energy levels 2, 8, 14, 2 |
156 | Rh Rhodium
: number of electron by energy levels 2, 8, 18, 16, 1 |
173 | Pt Platinium
: number of electron by energy levels 2, 8, 18, 32, 17, 1 |
177 |
| O Oxygen
: number of electron by energy levels 2, 6 |
48 | Co Cobalt
: number of electron by energy levels 2, 8, 15, 2 |
152 | Pd Palladium
: number of electron by energy levels 2, 8, 18, 18 |
169 | Au Gold
: number of electron by energy levels 2, 8, 18, 32, 18, 1 |
174 |
| F Fluorine
: number of electron by energy levels 2, 7 |
42 | Ni Nickel
: number of electron by energy levels 2, 8, 16, 2 or 2, 8, 17, 1 |
149 | Ag Silver
: number of electron by energy levels 2, 8, 18, 18, 1 |
165 | Hg Mercury
: number of electron by energy levels 2, 8, 18, 32, 18, 2 |
171 |
| Ne Neon
: number of electron by energy levels 2, 8 |
38 | Cu Copper
: number of electron by energy levels 2, 8, 18, 1 |
145 | Cd Cadmium
: number of electron by energy levels 2, 8, 18, 18, 2 |
161 | TL Thallium
: number of electron by energy levels 2, 8, 18, 32, 18, 3 |
156 |
| Na Sodium
: number of electron by energy levels 2, 8, 1 |
190 | Zn Zinc
: number of electron by energy levels 2, 8, 18, 2 |
142 | In Indium
: number of electron by energy levels 2, 8, 18, 18, 3 |
156 | Pb Lead
: number of electron by energy levels 2, 8, 18, 32, 18, 4 |
154 |
| Mg Magnesium
: number of electron by energy levels 2, 8, 2 |
145 | Ga Gallium
: number of electron by energy levels 2, 8, 18, 3 |
136 | Sn Tin
: number of electron by energy levels 2, 8, 18, 18, 4 |
145 | Bi Bismuth
: number of electron by energy levels 2, 8, 18, 32, 18, 5 |
143 |
| Al Aluminium
: number of electron by energy levels 2, 8, 3 |
118 | Ge Germanium
: number of electron by energy levels 2, 8, 18, 4 |
125 | Sb Antimony
: number of electron by energy levels 2, 8, 18, 18, 5 |
133 | Po Polonium
: number of electron by energy levels 2, 8, 18, 32, 18, 6 |
135 |
| Si Silicon
: number of electron by energy levels 2, 8, 4 |
111 | As Arsenic
: number of electron by energy levels 2, 8, 18, 5 |
114 | Te Tellurium
: number of electron by energy levels 2, 8, 18, 18, 6 |
123 | At Astatine
: number of electron by energy levels 2, 8, 18, 32, 18, 7 |
127 |
| P Phosphorus
: number of electron by energy levels 2, 8, 5 |
98 | Se Selenium
: number of electron by energy levels 2, 8, 18, 6 |
103 | I Iodine
: number of electron by energy levels 2, 8, 18, 18, 7 |
115 | Rn Radon
: number of electron by energy levels 2, 8, 18, 32, 18, 8 |
120 |
| S Sulfur
: number of electron by energy levels 2, 8, 6 |
88 | Br Bromine
: number of electron by energy levels 2, 8, 18, 7 |
94 | Xe Xenon
: number of electron by energy levels 2, 8, 18, 18, 8 |
108 | ||
| Cl Clorine
: number of electron by energy levels 2, 8, 7 |
79 | Kr Krypton
: number of electron by energy levels 2, 8, 18, 8 |
88 | Cs Caesium
: number of electron by energy levels 2, 8, 18, 18, 8, 1 |
298 | ||
| Ar Argon
: number of electron by energy levels 2, 8, 8 |
71 | Rb Rubidium
: number of electron by energy levels 2, 8, 18, 8, 1 |
265 | Ba Barium
: number of electron by energy levels 2, 8, 18, 18, 8, 2 |
253 | ||
| K Potassium
: number of electron by energy levels 2, 8, 8, 1 |
243 | Sr Strontium
: number of electron by energy levels 2, 8, 18, 8, 2 |
219 | Lu Lutetium
: number of electron by energy levels 2, 8, 18, 32, 9, 2 |
217 | ||